Diastereoselectivity and molecular recognition of mercury(II) ions

Hdl Handle:
http://hdl.handle.net/10149/596740
Title:
Diastereoselectivity and molecular recognition of mercury(II) ions
Authors:
Reynal, A. (Anna); Albero, J. (Josep); Vidal-Ferran, A. (Anton); Palomares, E. (Emilio)
Affiliation:
Teesside University, School of Science & Engineering.
Citation:
Reynal, A.; Albero, J.; Vidal-Ferran, A.; Palomares, E. (2009) 'Diastereoselectivity and molecular recognition of mercury(II) ions' Inorganic Chemistry Communications; 12 (2): 131-134
Publisher:
Elsevier
Journal:
Inorganic Chemistry Communications
Issue Date:
Feb-2009
URI:
http://hdl.handle.net/10149/596740
DOI:
10.1016/j.inoche.2008.11.029
Additional Links:
http://linkinghub.elsevier.com/retrieve/pii/S1387700308004334
Abstract:
Two diastereoisomers of a new heteroleptic ruthenium cis-dithiocyanate dicarboxy-bipyridyl phenanthrolyl complex have been synthesized and characterized. This type of complexes can selectively bind mercury ions through the sulphur atoms on the thiocyanate groups. The properties of these complexes as chemosensor towards Hg2+ in solution and anchored onto a mesoporous Al2O3 film have been studied and analysed. A different level of sensitivity versus mercury ions in aqueous solutions was observed for each stereoisomer.
Type:
Article
Language:
en
Keywords:
Colorimetric; Ruthenium complex; Mercury; Chemosensor; Diastereoselective
ISSN:
13877003
Rights:
Author can archive post-print (ie final draft post-refereeing) after an embargo from publication. For full details see http://www.sherpa.ac.uk/romeo [Accessed 19/02/2016]

Full metadata record

DC FieldValue Language
dc.contributor.authorReynal, A. (Anna)en
dc.contributor.authorAlbero, J. (Josep)en
dc.contributor.authorVidal-Ferran, A. (Anton)en
dc.contributor.authorPalomares, E. (Emilio)en
dc.date.accessioned2016-02-19T14:50:11Zen
dc.date.available2016-02-19T14:50:11Zen
dc.date.issued2009-02en
dc.identifier.citationInorganic Chemistry Communications; 12 (2): 131-134en
dc.identifier.issn13877003en
dc.identifier.doi10.1016/j.inoche.2008.11.029en
dc.identifier.urihttp://hdl.handle.net/10149/596740en
dc.description.abstractTwo diastereoisomers of a new heteroleptic ruthenium cis-dithiocyanate dicarboxy-bipyridyl phenanthrolyl complex have been synthesized and characterized. This type of complexes can selectively bind mercury ions through the sulphur atoms on the thiocyanate groups. The properties of these complexes as chemosensor towards Hg2+ in solution and anchored onto a mesoporous Al2O3 film have been studied and analysed. A different level of sensitivity versus mercury ions in aqueous solutions was observed for each stereoisomer.en
dc.language.isoenen
dc.publisherElsevieren
dc.relation.urlhttp://linkinghub.elsevier.com/retrieve/pii/S1387700308004334en
dc.rightsAuthor can archive post-print (ie final draft post-refereeing) after an embargo from publication. For full details see http://www.sherpa.ac.uk/romeo [Accessed 19/02/2016]en
dc.subjectColorimetricen
dc.subjectRuthenium complexen
dc.subjectMercuryen
dc.subjectChemosensoren
dc.subjectDiastereoselectiveen
dc.titleDiastereoselectivity and molecular recognition of mercury(II) ionsen
dc.typeArticleen
dc.contributor.departmentTeesside University, School of Science & Engineering.en
dc.identifier.journalInorganic Chemistry Communicationsen
or.citation.harvardReynal, A.; Albero, J.; Vidal-Ferran, A.; Palomares, E. (2009) 'Diastereoselectivity and molecular recognition of mercury(II) ions' Inorganic Chemistry Communications; 12 (2): 131-134en
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