The Infrared Spectrum of Isotopomers of the TeH Radical, Observed by CO Laser Magnetic Resonance

Hdl Handle:
http://hdl.handle.net/10149/98592
Title:
The Infrared Spectrum of Isotopomers of the TeH Radical, Observed by CO Laser Magnetic Resonance
Authors:
Gillett, D. A. (David); Towle, J. P. (Jonathan); Islam, M. (Meezanul); Brown, J. M. (John)
Affiliation:
University of Oxford. Physical/Theoretical Chemistry Laboratory.
Citation:
Gillett, D. A. et. al. (1994) 'The Infrared Spectrum of Isotopomers of the TeH Radical, Observed by CO Laser Magnetic Resonance', Journal of Molecular Spectroscopy, 163 (2), pp.459-482.
Publisher:
Elsevier
Journal:
Journal of Molecular Spectroscopy
Issue Date:
Feb-1994
URI:
http://hdl.handle.net/10149/98592
DOI:
10.1006/jmsp.1994.1040
Abstract:
The infrared spectrum of the TeH radical in its X2Π state has been recorded using an intracavity CO laser magnetic resonance (LMR) spectrometer. Seven of the eight naturally occurring Te isotopomers were observed, with resonances originating from the first three vibrational levels; many were recorded as Lamb-dips. These observations have been combined with existing data for TeH and TeD in the X2Π state and used to determine the parameters of an N2 Hamiltonian, including isotopic scaling and nonadiabatic corrections. The data are well described by the parameters. The different isotopic dependences of the effects of the parameters AD and γ has allowed their separation and the extent to which TeH shows Hund′s case (c) coupling is discussed. Trends displayed by the chalcogen monohydrides are considered.
Type:
Article
Language:
en
Keywords:
infrared spectroscopy; laser applications; magnetic resonance; spectroscopic analysis; tellurium compounds
ISSN:
0022-2852; 1096-083X
Rights:
Author can archive post-print (ie final draft post-refereeing). For full details see http://www.sherpa.ac.uk/romeo/ [Accessed 12/05/2010]
Citation Count:
4 [Scopus, 12/05/2010]

Full metadata record

DC FieldValue Language
dc.contributor.authorGillett, D. A. (David)en
dc.contributor.authorTowle, J. P. (Jonathan)en
dc.contributor.authorIslam, M. (Meezanul)en
dc.contributor.authorBrown, J. M. (John)en
dc.date.accessioned2010-05-12T12:24:01Z-
dc.date.available2010-05-12T12:24:01Z-
dc.date.issued1994-02-
dc.identifier.citationJournal of Molecular Spectroscopy; 163(2):459-482en
dc.identifier.issn0022-2852-
dc.identifier.issn1096-083X-
dc.identifier.doi10.1006/jmsp.1994.1040-
dc.identifier.urihttp://hdl.handle.net/10149/98592-
dc.description.abstractThe infrared spectrum of the TeH radical in its X2Π state has been recorded using an intracavity CO laser magnetic resonance (LMR) spectrometer. Seven of the eight naturally occurring Te isotopomers were observed, with resonances originating from the first three vibrational levels; many were recorded as Lamb-dips. These observations have been combined with existing data for TeH and TeD in the X2Π state and used to determine the parameters of an N2 Hamiltonian, including isotopic scaling and nonadiabatic corrections. The data are well described by the parameters. The different isotopic dependences of the effects of the parameters AD and γ has allowed their separation and the extent to which TeH shows Hund′s case (c) coupling is discussed. Trends displayed by the chalcogen monohydrides are considered.en
dc.language.isoenen
dc.publisherElsevieren
dc.rightsAuthor can archive post-print (ie final draft post-refereeing). For full details see http://www.sherpa.ac.uk/romeo/ [Accessed 12/05/2010]en
dc.subjectinfrared spectroscopyen
dc.subjectlaser applicationsen
dc.subjectmagnetic resonanceen
dc.subjectspectroscopic analysisen
dc.subjecttellurium compoundsen
dc.titleThe Infrared Spectrum of Isotopomers of the TeH Radical, Observed by CO Laser Magnetic Resonanceen
dc.typeArticleen
dc.contributor.departmentUniversity of Oxford. Physical/Theoretical Chemistry Laboratory.en
dc.identifier.journalJournal of Molecular Spectroscopyen
ref.citationcount4 [Scopus, 12/05/2010]en
or.citation.harvardGillett, D. A. et. al. (1994) 'The Infrared Spectrum of Isotopomers of the TeH Radical, Observed by CO Laser Magnetic Resonance', Journal of Molecular Spectroscopy, 163 (2), pp.459-482.-
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