Hdl Handle:
http://hdl.handle.net/10149/98854
Title:
Dynamic methods for catalytic kinetics
Authors:
Berger, R. J. (Rob); Kapteijn, F. (Freek); Moulijn, J. A. (Jacob); Marin, G. B. (Guy); de Wilde, J. (Juray); Olea, M. (Maria); Chen, D. (De); Holmen, A. (Anders); Lietti, L. (Luca); Tronconi, E. (Enrico); Schuurman, Y. (Yves)
Affiliation:
Ghent University
Citation:
Berger, R. J. et. al. (2008) 'Dynamic methods for catalytic kinetics', Applied Catalysis A General, 342 (1-2), pp.3-28.
Publisher:
Elsevier
Journal:
Applied Catalysis A General
Issue Date:
30-Jun-2008
URI:
http://hdl.handle.net/10149/98854
DOI:
10.1016/j.apcata.2008.03.020
Abstract:
The application of various transient techniques in heterogeneous catalysis (TAP, step-response experiments, SSITKA, TEOM), with the aim to determine reaction kinetics for design purposes, is presented for several cases. These cases, comprising catalytic cracking, diffusion in zeolites, simultaneous NOx and SOx removal, syngas production from methane by chemical looping and selective catalytic reduction of NOx, show that transient techniques can be well used for the purpose of rapid determination of the reaction kinetics without the laborious classical approach of steady-state kinetic measurements and without the need of high levels of sophistication to interpret and process the experimental data. In this respect transient kinetics deserve, next to fundamental catalysis studies, more frequent application in design studies for industrially relevant reaction systems. Topics and challenges for further developments in transient studies are indicated.
Type:
Article
Language:
en
Keywords:
catalytic cracking; chemical looping; concentration programming; diffusion in zeolites; heterogeneous catalysis; isotopic labeling; kinetics; methane coupling; SCR; SOx and NOx removal; SSITKA; step-response experiments; TAP; temperature programming; TEOM; transient technique
ISSN:
0926-860X
Rights:
Author can archive post-print (ie final draft post-refereeing). For full details see http://www.sherpa.ac.uk/romeo/ [Accessed 14/05/2010]
Citation Count:
7 [Scopus, 14/05/2010]

Full metadata record

DC FieldValue Language
dc.contributor.authorBerger, R. J. (Rob)en
dc.contributor.authorKapteijn, F. (Freek)en
dc.contributor.authorMoulijn, J. A. (Jacob)en
dc.contributor.authorMarin, G. B. (Guy)en
dc.contributor.authorde Wilde, J. (Juray)en
dc.contributor.authorOlea, M. (Maria)en
dc.contributor.authorChen, D. (De)en
dc.contributor.authorHolmen, A. (Anders)en
dc.contributor.authorLietti, L. (Luca)en
dc.contributor.authorTronconi, E. (Enrico)en
dc.contributor.authorSchuurman, Y. (Yves)en
dc.date.accessioned2010-05-14T15:07:12Z-
dc.date.available2010-05-14T15:07:12Z-
dc.date.issued2008-06-30-
dc.identifier.citationApplied Catalysis A General; 342(1-2):3-28en
dc.identifier.issn0926-860X-
dc.identifier.doi10.1016/j.apcata.2008.03.020-
dc.identifier.urihttp://hdl.handle.net/10149/98854-
dc.description.abstractThe application of various transient techniques in heterogeneous catalysis (TAP, step-response experiments, SSITKA, TEOM), with the aim to determine reaction kinetics for design purposes, is presented for several cases. These cases, comprising catalytic cracking, diffusion in zeolites, simultaneous NOx and SOx removal, syngas production from methane by chemical looping and selective catalytic reduction of NOx, show that transient techniques can be well used for the purpose of rapid determination of the reaction kinetics without the laborious classical approach of steady-state kinetic measurements and without the need of high levels of sophistication to interpret and process the experimental data. In this respect transient kinetics deserve, next to fundamental catalysis studies, more frequent application in design studies for industrially relevant reaction systems. Topics and challenges for further developments in transient studies are indicated.en
dc.language.isoenen
dc.publisherElsevieren
dc.rightsAuthor can archive post-print (ie final draft post-refereeing). For full details see http://www.sherpa.ac.uk/romeo/ [Accessed 14/05/2010]en
dc.subjectcatalytic crackingen
dc.subjectchemical loopingen
dc.subjectconcentration programmingen
dc.subjectdiffusion in zeolitesen
dc.subjectheterogeneous catalysisen
dc.subjectisotopic labelingen
dc.subjectkineticsen
dc.subjectmethane couplingen
dc.subjectSCRen
dc.subjectSOx and NOx removalen
dc.subjectSSITKAen
dc.subjectstep-response experimentsen
dc.subjectTAPen
dc.subjecttemperature programmingen
dc.subjectTEOMen
dc.subjecttransient techniqueen
dc.titleDynamic methods for catalytic kineticsen
dc.typeArticleen
dc.contributor.departmentGhent Universityen
dc.identifier.journalApplied Catalysis A Generalen
ref.citationcount7 [Scopus, 14/05/2010]en
or.citation.harvardBerger, R. J. et. al. (2008) 'Dynamic methods for catalytic kinetics', Applied Catalysis A General, 342 (1-2), pp.3-28.-
All Items in TeesRep are protected by copyright, with all rights reserved, unless otherwise indicated.